Diastereoselective hydrogenations of α-alkyl α-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)methylene carbonyl compounds. New route to stereopure α-alkyl α-oxymethyl carbonyl compounds

DOI: 10.1039/P19960002487

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2487 - 2495 (1996)

Update date:2022-08-04

Topics:

Authors:

Larsen, David S.

Schofield, Anthony

Stoodley, Richard J.

Tiffin, Peter D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19960002487

Wittig condensation of the stabilised phosphoranes 9, 10 and 26 with 1-formyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranose 11 leads to the vinylogous carbonates 12, 13 and 22. The salts 27-30 and 44, prepared from the corresponding carbonyl compounds, ethyl f

Full text of DOI:10.1039/P19960002487

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(E)-2-(2',3',4',6'-Tetra-O-acetyl-β-D-glucopyranosyloxymethylene)cyclohexanone

Cas No:184824-72-4

R&D Labs maybe for 184824-72-4

Tianjin Bright Future Technology Co., Ltd

Contact:0086-22-58016666

Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district
Lanzhou huibang biological chemical technology Co., LTD

Contact:0931-7843964

Address:NO.2011,Yannan Road,Chengguan,
xujianqiang

Contact:86-21-57725962

Address:shanghai

Relevant to this article

Synthesis and in vitro activity of 3β-substituted-3α-hydroxypregnan- 20-ones: Allosteric modulators of the GABA(A) receptor

Doi:10.1021/jm960021x
(1997)
S-oxidation products of alkylthioamphetamines

Doi:10.1081/SCC-120006041
(2002)
Benzoxazines. II. Synthesis, conformational analysis, and structure- activity relationships of 3,4-dihydro-2H-1,4-benzoxazine-8-carboxamide derivatives as potent and long-acting serotonin-3 (5-HT₃) receptor antagonists

Doi:10.1248/cpb.44.2051
(1996)
The synthesis of tenuazonic and congeneric tetramie acids.

Doi:10.1021/jm00328a014
(1965)
The synthesis and characterisation of a novel thiophene-based liquid crystal exhibiting ferro-, ferri- and antiferro-electric phase types

Doi:10.1039/jm9960601871
(1996)
A unique nido exo-arachno equilibrium involving [(PPh₃)₂(CO)OsB₅H₉] and its base adducts: Crystal and molecular structure of [{(PPh₃)₂(CO)OsB₄H₇}(bh₂·PPh₂Me)]

Doi:10.1021/ja962192x
(1997)

Article Doi