Journal of the Chemical Society, Dalton Transactions p. 4063 - 4069 (1996)
Update date:2022-08-04
Topics:
Hankin, Danielle M.
Danopoulos, Andreas A.
Wilkinson, Geoffrey
Sweet, Tracy K. N.
Hursthouse, Michael B.
The interaction of [Ru(η-C5Me5)Cl2]2 with Li(ButNSPh), gave two products, Ru(η4-C5Me4CH2)(η 2-ButNSPh)Cl 1 and the dimer Cl(η-C5Me5)Ru(μ-NBu t)(μ-SPh)Ru(η-C5Me5) 2; the former is best described as a η4-tetramethylfulvene ruthenium(II) complex, while in the latter the bridging tert-butylimido and benzenethiolato groups were formed by S-N cleavage of sulfenamido species. A similar cleavage resulted in the formation of CrV(η-C5Me5)(NBut)(SPh) 2 3, in the interaction of Li(ButNSPh) with [Cr(η-C5Me5)Br2]2. Interaction of CoCl2(PMe3)3 with Li(p-MeC6H4NSPh) gave the iminophosphorane complex Co(p-MeC6H4NPMe3)2(SPh)2 4. Interaction of NiCl2(PMe3)2 with Li(ButNSPh) gave Ni(η2-ButNSPh)2(PMe3) 5. The structures of compounds 1-5 have been confirmed by X-ray crystallography.
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