Tetrahedron Letters p. 7897 - 7900 (1996)
Update date:2022-08-03
Topics:
Zhang, Han-Cheng
Harris, Bruce D.
Maryanoff, Cynthia A.
Maryanoff, Bruce E.
Reduction of acyclic ε-hydroxy ketone 3 with R-Alpine-Hydride in methylene chloride provided a strong preponderance of the anti diasteromer of 4 (anti:syn = 12:1). This impressive 1,6 stereoselectivity is attributed to bicyclic chelation control of hydride addition.
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