Highly efficient synthesis of alka-1,3-dien-2-yltitanium compounds from alka-2,3-dienyl carbonates. A new, practical synthesis of 1,3-dienes and 2-iodo-1,3-dienes

DOI: 10.1016/S0040-4039(96)02126-0

Source and publish data:

Tetrahedron Letters p. 8865 - 8868 (1996)

Update date:2022-09-26

Topics:

Authors:

Okamoto, Sentaro

Sato, Hiroyoshi

Sato, Fumie

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(96)02126-0

Treatment of carbonates of alka-2,3-dien-1-ols 2 with (η²-propene)Ti(O-i-Pr)₂ (1) resulted in oxidative addition to afford 1,3-dien-2-yltitanium compounds 3, which react readily with electrophiles such as H⁺, I₂

Full text of DOI:10.1016/S0040-4039(96)02126-0

Products guided by the article

Product name:Carbonic acid, ethyl 1-phenyl-2,3-butadienyl ester

Cas No:185451-56-3

R&D Labs maybe for 185451-56-3

Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Jiangsu Hualun Chemical Industry Co., Ltd

website:http://www.hualunchem.com

Contact:+86-0514-86464168 86507985

Address:39# Middle Renmin Road, Dinghuo Town
Fusilin chemical science & technology co., ltd.

Contact:532-80698166/86057573, +86-400-669-7885

Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong
JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP
Beijing Pure Chem Co.,Ltd.

Contact:+86-10-83993285

Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China

Relevant to this article

Molecular Complexes. Part 18. -A Nuclear Magnetic Resonance Adaptation of the Continuous Variation (Job) Method of Stoicheiometry Determination

Doi:10.1039/f19868200533
(1986)
Synthesis and biological activities of three sulfated sialyl Le(x) ganglioside analogues for clarifying the real carbohydrate ligand structure of L-selectin

Doi:10.1016/S0968-0896(96)00165-4
(1996)
Green and Efficient Synthesis of 4-Heteryl-Quinolines and Their Antibacterial Evaluations

Doi:10.1002/jhet.2698
(2017)
Synthesis of β-hydroxypiperidine alkaloids by anodic oxidation of carbamates and hydroboration

Doi:10.1139/v96-273
(1996)
O₂ activation and aromatic hydroxylation performed by diiron complexes

Doi:10.1021/ja981123a
(1998)
Total synthesis of (+)-isolaurepinnacin. Use of acetal-alkene cyclizations to prepare highly functionalized seven-membered cyclic ethers

Doi:10.1021/ja964080b
(1997)

Article Doi