Synthetic entry into the ent-kaurene framework. Application of an unprecedented transannular cyclization for forming the central bond common to the B and C rings

DOI: 10.1016/S0040-4039(96)02247-2

Source and publish data:

Tetrahedron Letters p. 29 - 32 (1997)

Update date:2022-08-03

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Authors:

Backhaus, Dirk

Paquette, Leo A.

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Article abstract of DOI:10.1016/S0040-4039(96)02247-2

A stereocontrolled means for constructing the ent-kaurene framework is described. The key transformation involves transannular ring closure of an 8,9-seco precursor with migration of an interstitial methoxyl group.

Full text of DOI:10.1016/S0040-4039(96)02247-2

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