A new and efficient synthesis of α-amino cycloalkylphosphonic acids via electrophilic azidation of cycloalkylphosphonates

Article abstract of DOI:10.1080/00397919608004650

α-Amino cyclobutyl-, cyclopentyl- and cyclohexylphosphonic acids (13) were efficiently prepared from the related unsubstituted cycloalkylphosphonates (5), in three steps including electrophilic azidation of the corresponding lithiated carbanions, catalyti

Full text of DOI:10.1080/00397919608004650

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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A New and Efficient Synthesis
of α-Amino Cycloalkyl-
Phosphonic Acids via
Electrophilic Azidation of
Cycloalkylphosphonates
Catherine Guéguen a , Elie About-Jaude a , Noël
Collignon a & Philippe Savignac b
a Laboratoire d'Hétérochimie Organique , INSA-
IRCOF , BP 08, 76131, Mont-Saint-Aignan, Cedex,
FRANCE
b Hétéroéléments et Coordination , URA CNRS ,
1499, DCPH, Ecole Polytechnique, 91128, Palaiseau,
Cedex, FRANCE
Published online: 19 Aug 2006.
To cite this article: Catherine Guéguen , Elie About-Jaude , Noël Collignon & Philippe
Savignac (1996) A New and Efficient Synthesis of α-Amino Cycloalkyl-Phosphonic Acids
via Electrophilic Azidation of Cycloalkylphosphonates, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 26:22,
4131-4143, DOI: 10.1080/00397919608004650
To link to this article: http://dx.doi.org/10.1080/00397919608004650
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