Mixed co-ordination numbers and geometries of gold(I) in a dinuclear complex of thioglycerol

DOI: 10.1039/DT9960004511

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 4511 - 4512 (1996)

Update date:2022-08-05

Topics: Dinuclear Complex Experimental terms

Authors:

Lopez-De-Luzuriaga, Jose M.

Sladek, Alexander

Schmidbaur, Hubert

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Article abstract of DOI:10.1039/DT9960004511

Reaction of DL-3-sulfanylpropane-1,2-diol with [O(AuPPh₃)₃]BF₄ afforded a dinuclear complex [Au₂(PPh₃)₃{SCH₂CH(OH)CH ₂OH}] in which two gold environments, linear and trigonal planar, are present in the same molecule; the complex has been structurally characterized.

Full text of DOI:10.1039/DT9960004511

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Product name:Au₂(P(C₆H₅)3)3(SCH₂CH(OH)CH₂OH)⁽¹⁺⁾*BF₄^(1-) = [Au₂(P(C₆H₅)3)3(SCH₂CH(OH)CH₂OH)]BF₄

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