Tetrahedron Letters p. 3695 - 3698 (1993)
Update date:2022-08-05
Topics: alkenes Reactions Stereoselective Experimental Organocopper reagents
Chauret, Denise C.
Chong, J. Michael
Reactions of α-epoxysilanes with cuprate reagents can be controlled to give β-silyl alcohols as major products. An oxidation, Grignard addition, and elimination sequence then provides alkenes with up to 98% de.
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