An unusual thermodynamic preference of chiral N-arylsulfonyl cis-3-alkyl-2-vinylaziridines over their trans-isomers: Palladium(0)-catalysed equilibration reactions

DOI: 10.1039/cc9960000351

Source and publish data:

Chemical Communications p. 351 - 352 (1996)

Update date:2022-08-05

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Authors:

Mimura, Norio

Ibuka, Toshiro

Akaji, Masako

Miwa, Yoshihisa

Taga, Tooru

Nakai, Kazuo

Tamamura, Hirokazu

Fujii, Nobutaka

Yamamoto, Yoshinori

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Article abstract of DOI:10.1039/cc9960000351

Palladium (0)-catalysed reactions of N-alkylsulfonyl- or N-arylsulfonyl-3-alkyl-2-vinylaziridines reveal that 2,3-cis-isomers are more stable than the corresponding 2,3-trans-isomers in accord with ab initio calculations.

Full text of DOI:10.1039/cc9960000351

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