Tetrahedron Letters p. 769 - 772 (1997)
Update date:2022-08-03
Topics:
Ramachandran, P. Veeraraghavan
Wei-Chu, Xu
Brown, Herbert C.
The easily synthesized B,B-dihaloalkylboranes, in the presence of either Et3N or i-Pr2NEt, converts ethyl ketones, RCOEt, to 96-≤ 99% Z-enolates, converted by aldehydes to essentially pure syn-aldols.
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