First total synthesis of (+)-caparratriene

DOI: 10.1246/cl.1997.229

Source and publish data:

Chemistry Letters p. 229 - 230 (1997)

Update date:2022-07-30

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Authors:

Li, Jing

Liu, Zuosheng

Lan, Jiong

Li, Yulin

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Article abstract of DOI:10.1246/cl.1997.229

Caparratriene (1), a new sesquiterpene hydrocarbon with significant growth inhibitory activity against CEM leukemia cells, was first synthesized starting from (R)-(+)-citronellal through 3 steps in an overall yield of 17.5%. The absolute configuration at

Full text of DOI:10.1246/cl.1997.229

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Product name:tert-Butyl-diphenyl-((2E,4E)-(R)-3,7,11-trimethyl-dodeca-2,4,10-trienyloxy)-silane

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