2-Alkenyl dioxolanylium cations, new reactive dienophiles in low temperature asymmetric Diels-Alder reactions

DOI: 10.1016/S0957-4166(96)00470-3

Source and publish data:

Tetrahedron Asymmetry p. 139 - 148 (1997)

Update date:2022-07-30

Topics:

Authors:

Haudrechy, Arnaud

Picoul, Willy

Langlois, Yves

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0957-4166(96)00470-3

Chiral orthoesters 14-22 were prepared by an exchange reaction with orthoester 13. These compounds, after treatment with trimethylsilyltriflate or tin(IV) chloride, gave rise to vinyl dioxolanylium cations which proved to be very reactive dienophils in various Diels-Alder reactions.

Full text of DOI:10.1016/S0957-4166(96)00470-3

Products guided by the article

Product name:(R)-2-(3-Methoxy-benzyloxymethyl)-1,4-dioxa-spiro[4.5]decane

Cas No:188303-56-2

R&D Labs maybe for 188303-56-2

HAORUI ENTERPRISES LLC

Contact:(1) 206-3550089

Address:5115 NE 8TH PL, Renton, WA 98059 USA
C-LAB Chemievermittlung GmbH

Contact:+49-9398-993127

Address:Untertorstr. 27
Xinjiang Zhongtai Chemical Co., Ltd.

Contact:+86-991-8788172

Address:NO.78 XISHAN RD.URUMQI，CHINA
NOVASYNCS CO., LTD

Contact:0512-63006287

Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-5161 3915

Address:Shanghai YangPu

Relevant to this article

Autoxidation of pyrrolylurethanes

Doi:10.1016/S0040-4039(97)00075-0
(1997)
A new synthesis of macrotricyclic ligand based on 1,4,8,11-tetraazacyclotetradecane

Doi:10.1080/00397919708003042
(1997)
Enantioselective synthesis of haminol-1, an alarm pheromone of a Mediterranean mollusc

Doi:10.1016/S0957-4166(97)00025-6
(1997)
Reduction of Biginelli compounds by LiAlH₄: a rapid access to molecular diversity

Doi:10.1039/c6ra24535h
(2016)
Facile synthesis of (S)-β-hydroxy-β-trichloromethylated aromatic ketones by the regioselective ring cleavage of chiral β-trichloromethyl-β-propiolactone under the Friedel-Crafts conditions

Doi:10.1016/S0040-4039(97)00120-2
(1997)
Total synthesis of the antiproliferative macrolide (+)-neopeltolide

Doi:10.1021/ol902047z
(2009)

Article Doi