Highly stereoselective tandem Pummerer reaction/α-hydroxy imine rearrangement of e.P. β-sulfinylenamines

Article abstract of DOI:10.1080/10426509708545545

The highly stereoselective tandem Pummerer reaction/α-hydroxy imine rearrangement of E.P. α-fluoroalkyl-β-sulfinylenamines affording chiral non-racemic fluoropyruvaldehydes N,S-ketals is described.

Full text of DOI:10.1080/10426509708545545

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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Highly Stereoselective Tandem
Pummerer Reaction/α-Hydroxy
Imine Rearrangement of E.P. β-
Sulfinylenamines
Pierfrancesco Bravo , Marcello Crucianelli , Alessandro
Volonterio & Matteo Zanda
a C.N.R. - C.S.S.O.N. Dipartimento di Chimica del
Politecnico , via Mancinelli 7, I-20131 Milano, Italy
b C.N.R. - C.S.S.O.N. Dipartimento di Chimica del
Politecnico , via Mancinelli 7, I-20131 Milano, Italy
c C.N.R. - C.S.S.O.N. Dipartimento di Chimica del
Politecnico , via Mancinelli 7, I-20131 Milano, Italy
d C.N.R. - C.S.S.O.N. Dipartimento di Chimica del
Politecnico , via Mancinelli 7, I-20131 Milano, Italy
Published online: 17 Mar 2008.
To cite this article: Pierfrancesco Bravo , Marcello Crucianelli , Alessandro Volonterio &
Matteo Zanda (1997) Highly Stereoselective Tandem Pummerer Reaction/α-Hydroxy Imine
Rearrangement of E.P. β-Sulfinylenamines, Phosphorus, Sulfur, and Silicon and the Related
Elements, 120:1, 353-354, DOI: 10.1080/10426509708545545
To link to this article: http://dx.doi.org/10.1080/10426509708545545
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