An enantio- and diastereo-controlled synthesis of (-)neplanocin A and its 2,3-di-epi isomer

DOI: 10.1016/S0040-4039(97)00176-7

Source and publish data:

Tetrahedron Letters p. 1707 - 1710 (1997)

Update date:2022-08-04

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Authors:

Trost, Barry M.

Madsen, Robert

Guile, Simon D.

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Article abstract of DOI:10.1016/S0040-4039(97)00176-7

An enantioselective Pd catalyzed desymmetrization of cis-3,5-dibenzoyloxycyclopent-2-ene combined with a diastereoselective epoxidation provided a common intermediate that can bifurcate to form either (-)-neplanocin A or its 2,3-di-epi isomer.

Full text of DOI:10.1016/S0040-4039(97)00176-7

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