Angewandte Chemie - International Edition in English p. 502 - 504 (1997)
Update date:2022-07-30
Topics:
Bogdanovic
Leitner
Six
Wilczok
Wittmann
Interesting stoichiometric and catalytic reactions are possible with the rhodium phosphane complexes [{Ph2P(CH2)(n)PPh2)(n)}2Rh][MgC1] (1: a, n = 2; b, n = 3), which are readily accessible by reaction of the chloride complexes 2 with active magnesium. The 'Grignard-analogous' compounds 1 react to form 3 (E = H, Me SiMe3) by protolysis, alkylation, and silylation. The interconversion of complexes 2a and 1a can be used for catalytic transfer of two electrons from magnesium to CO2 to yield CO and CO3/2+.
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Doi:10.1021/jo01256a029
(1969)Doi:10.1021/ja01856a032
(1941)Doi:10.1021/jo962371x
(1997)Doi:10.1515/znb-1999-0517
(1999)Doi:10.1016/S0040-4039(97)00966-0
(1997)Doi:10.1016/S0008-6215(97)00032-3
(1997)
