Tetrahedron p. 5083 - 5102 (1997)
Update date:2022-07-31
Topics:
Tsuboi, Katsunori
Ichikawa, Yoshiyasu
Naganawa, Atsushi
Isobe, Minoru
Ubukata, Makoto
Isono, Kiyoshi
The synthesis of Segment B corresponding to the C26-C17 portion of tautomycin was accomplished by coupling reaction between the epoxide (Sub-segment B-l) and the dithiane (Subsegment B-2). The degradation product of tautomycin corresponding to the C26-C19 portion was also synthesized from Sub-segment B-1.
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