The reaction of with thiols: a 1H and 31P NMR study

DOI: 10.1016/0022-328X(90)85398-I

Source and publish data:

Journal of Organometallic Chemistry p. 139 - 147 (1990)

Update date:2022-08-02

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Authors:

Carlton, Laurence

Bulbulia, Zaid

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Article abstract of DOI:10.1016/0022-328X(90)85398-I

In toluene or THF at -40 deg C (RhH(PPh3)4> reacts with RSH (R = Prⁱ, Ph, CH2Ph) to give the unstable dihydro complex .At 20 deg C decomposition of this complex with loss of H2 occurs via a five-coordinate species View More

Full text of DOI:10.1016/0022-328X(90)85398-I

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Product name:RhH(SPh)2(PPh₃)2(pyridine)

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