Dynamic kinetic protonation of racemic allenylmetal species for the asymmetric synthesis of allenic esters

DOI: 10.1002/anie.199708581

Source and publish data:

Angewandte Chemie - International Edition in English p. 858 - 860 (1997)

Update date:2022-08-03

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Authors:

Mikami Mikami

Yoshida Yoshida

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Article abstract of DOI:10.1002/anie.199708581

The selective protonation of one enantiomer in a racemic mixture of allenylmetal compounds is possible with Pd⁰/SmI₂ and a chiral alcohol (see reaction scheme below). The products, enantiomerically pure allenic esters, are an importa

Full text of DOI:10.1002/anie.199708581

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