Highly Stereoselective Synthesis of Tetrasubstituted Alkenes via -Wittig Rearrangement

DOI: 10.1016/0040-4039(94)88416-1

Source and publish data:

Tetrahedron Letters p. 9021 - 9024 (1994)

Update date:2022-08-05

Topics:

Authors:

Mulzer, Johann

List, Benjamin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(94)88416-1

A highly stereoselective synthesis of tetrasubstituted alkenes via the sequence Horner-Wadsworth-Emmons-, Grignard- and <2,3>-Wittig reaction is described, eight examples are given. - Keywords: <2,3-Wittig rearrangement, Claisen rearrangement, Horner-Wadsworth-Emmons reaction, tetrasubstituted alkenes.

Full text of DOI:10.1016/0040-4039(94)88416-1

Products guided by the article

Product name:(E)-(2R,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-3,4-dimethyl-8-trityloxy-oct-3-en-2-ol

Cas No:191034-60-3

R&D Labs maybe for 191034-60-3

Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
Wuxi D-Stone International Co., Ltd.

Contact:+86-510-82740567

Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China
Jiangxi Global Natural Spice Co., Ltd.

website:https://www.jxhqxl.com/

Contact:+86-796-8106598

Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
Yicheng Goto Pharmaceuticals Co.,Ltd.

Contact:+86 710 3423122

Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China
Simagchem Corporation

website:http://www.simagchem.com

Contact:+86-592-2680277

Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China

Relevant to this article

Structure-Elucidating Total Synthesis of the (Polyenoyl)tetramic Acid Militarinone C §

Doi:10.1021/acs.orglett.0c00431
(2020)
Cycloaromatization of a non-conjugated polyenyne system: Synthesis of 5H-benzo[d]fluoreno[3,2-b]pyrans via diradicals generated from 1-[2-{4-(2-alkoxymethylphenyl)butan-1,3-dinyl}]phenylpentan-2,4-diyn -1-ols and trapping evidence for the 1,2-didehydrobenzene diradical

Doi:10.1016/S0040-4039(97)00785-5
(1997)
Stereoselective synthesis of 2-deoxy-β-glycosides from glycal precursors. 2. Stereochemistry of glycosidation reactions of 2-thiophenyl- and 2-selenophenyl-α-D-gluco-pyranosyl donors

Doi:10.1016/S0040-4020(97)90395-1
(1997)
Immunogens from a synthetic hexasaccharide fragment of the O-SP of Vibrio cholerae O:1, serotype Ogawa

Doi:10.1016/j.tetasy.2004.11.021
(2005)
Palladium-Catalyzed Synthesis of Deuterated Alkenes through Deuterodechlorination of Alkenyl Chlorides

Doi:10.1021/acs.oprd.9b00193
(2019)
Doi:10.1007/BF00919154
(1965)

Article Doi