Highly Stereoselective Synthesis of Tetrasubstituted Alkenes via -Wittig Rearrangement

DOI: 10.1016/0040-4039(94)88416-1

Source and publish data:

Tetrahedron Letters p. 9021 - 9024 (1994)

Update date:2022-08-05

Topics:

Authors:

Mulzer, Johann

List, Benjamin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(94)88416-1

A highly stereoselective synthesis of tetrasubstituted alkenes via the sequence Horner-Wadsworth-Emmons-, Grignard- and <2,3>-Wittig reaction is described, eight examples are given. - Keywords: <2,3-Wittig rearrangement, Claisen rearrangement, Horner-Wadsworth-Emmons reaction, tetrasubstituted alkenes.

Full text of DOI:10.1016/0040-4039(94)88416-1

Products guided by the article

Product name:(E)-(2R,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-3,4-dimethyl-8-trityloxy-oct-3-en-2-ol

Cas No:191034-60-3

R&D Labs maybe for 191034-60-3

ORCHID CHEMICAL SUPPLIES LTD

website:http://www.orchid-chem.com

Contact:+86-571-85395792

Address:607, North Zhongshan Road, Hangzhou 310000 China
Taizhou Shengxing Chempharm Co.,Ltd

Contact:+86-576-88516600

Address:Yantou Chemical Zone Jiaojiang Taizhou Zhejiang China
GUANGZHOU MEDCAN PHARMATECH LTD

website:http://www.gzmedcan.com

Contact:+86-20-82519649

Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
Changsha Goomoo Chemical Technology Co.Ltd

Contact:+86-731-82197655

Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China

Relevant to this article

Structure-Elucidating Total Synthesis of the (Polyenoyl)tetramic Acid Militarinone C §

Doi:10.1021/acs.orglett.0c00431
(2020)
Cycloaromatization of a non-conjugated polyenyne system: Synthesis of 5H-benzo[d]fluoreno[3,2-b]pyrans via diradicals generated from 1-[2-{4-(2-alkoxymethylphenyl)butan-1,3-dinyl}]phenylpentan-2,4-diyn -1-ols and trapping evidence for the 1,2-didehydrobenzene diradical

Doi:10.1016/S0040-4039(97)00785-5
(1997)
Stereoselective synthesis of 2-deoxy-β-glycosides from glycal precursors. 2. Stereochemistry of glycosidation reactions of 2-thiophenyl- and 2-selenophenyl-α-D-gluco-pyranosyl donors

Doi:10.1016/S0040-4020(97)90395-1
(1997)
Immunogens from a synthetic hexasaccharide fragment of the O-SP of Vibrio cholerae O:1, serotype Ogawa

Doi:10.1016/j.tetasy.2004.11.021
(2005)
Palladium-Catalyzed Synthesis of Deuterated Alkenes through Deuterodechlorination of Alkenyl Chlorides

Doi:10.1021/acs.oprd.9b00193
(2019)
Doi:10.1007/BF00919154
(1965)

Article Doi