Synthesis of and asymmetric induction by chiral polycyclic thiazolium salts

DOI: 10.1016/S0040-4039(97)00682-5

Source and publish data:

Tetrahedron Letters p. 3615 - 3618 (1997)

Update date:2022-08-04

Topics:

Authors:

Gerhard, A. Ulrich

Leeper, Finian J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00682-5

Polycyclic thiazoles, 68 and b, have been synthesised and the enantiomers resolved. Alkylation gave chiral thiazolium salts which catalyse the dimerisation of benzaldehyde to give benzoin with enantiomeric excesses up to 26%. Reasons for these results are

Full text of DOI:10.1016/S0040-4039(97)00682-5

Products guided by the article

Product name:C₁₇H₁₄N₂O₂S

Cas No:191592-44-6

R&D Labs maybe for 191592-44-6

GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
guide(suzhou) fine materials co. ltd

Contact:0512-80972173

Address:21st Building, No.369 Lushan Rd, New District Suzhou China 215129
JiangXi Hong Run Chemical Co., Ltd

Contact:+86-0791-88521351

Address:XingHuo industrial zone in YongXiu county
SJZ THLD IMP & EXP CO LTD

website:http://www.truewingroup.com

Contact:86-311-66699812

Address:NO.600 ZHONGSHAN EAST ROAD SHIJIAZHUANG
Tianjin Pharmacn Medical Technology Co.,Ltd.

Contact:86-22-60122566ext.866(English),23359620

Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China

Relevant to this article

An efficient stereoselective synthesis of enantiomerically pure aziridine derivatives of allyl β-D-glucopyranosides asymmetrically induced by a glucide moiety

Doi:10.1016/S0957-4166(98)00427-3
(1998)
Palladium(II) complexes containing a P, N chelating ligand Part II . Synthesis and characterisation of complexes with different hydrazinic ligands. Catalytic activity in the hydrogenation of double and triple C-C bonds

Doi:10.1016/S0022-328X(96)06946-X
(1997)
Double isocyanide insertion and C,C-coupling reaction of [(C₅Me₄)SiMe₂(N-t-Bu)]ZrMe₂. Structural characterization of the two 1,4-diaza-5-zirconacyclopentene ring Conformations for [(C₅Me₄)SiMe₂(N-t-Bu)]Zr[N(R)C(Me)=C(Me)N(R)] complexes

Doi:10.1021/om9610760
(1997)
A novel method for suppression of the abnormal Fischer indole synthesis

Doi:10.1016/S0040-4020(97)90396-3
(1997)
Differential Bridging in the Solvolysis of Epimeric Bicyclic Sulfonates. Norbornanes, Part 17

Doi:10.1002/hlca.19840670311
(1984)
NOVEL SYNTHESIS OF N,N'-BIS(α-ISOCYANATO ALKYL)DIAZENES

Doi:10.1016/S0040-4020(01)91353-5
(1985)

Article Doi