Journal of Organometallic Chemistry p. 107 - 120 (1997)
Update date:2022-08-04
Topics:
Bacchi
Carcelli
Costa
Leporati
Leporati
Pelagatti
Pelizzi
Pelizzi
Palladium (II) complexes of the type Pd(PNO)Y (PNO = 2-(diphenylphosphino)benzaldehyde picolinhydrazone, nicotinhydrazone, isonicotinhydrazone; Y = CH3CO2, Cl, I) and Pd(PNS)Y (PNS = 2-(diphenylphosphino)benzaldehyde thiosemicarbazone; Y = CH3CO2, Cl, I) were synthesised and characterised by spectroscopic methods. The X-ray structure of an iodo complex was also determined. The catalytic activity of all the complexes in the homogeneous hydrogenation of terminal double and triple bonds was tested with particular regards to the chemoselectivity from triple to double bond. A correlation between the catalytic activity and the nature of the ligand and Y group was established. In the hydrogenation of phenylacetylene using acetato complexes as catalysts, stable phenylethynylpalladium(II) complexes were recovered and characterised by spectroscopic methods. A facile route of synthesis of alkynyl complexes was also determined.
View MoreSHANGHAI ARCADIA BIOTECHNOLOGY LTD.
Contact:+86-21-61353236
Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA
Xiamen Goodhealth Pharmchem Co., Ltd.
Contact:0086-592-2097683
Address:404R No.2 54# Minzu Rd., Xiamen, China
Contact:0510-85393305
Address:1619 Huishan Avenue, Huishan District, Wuxi,
Contact:86-21-50966856
Address:Building 5,300 Chuanzhan Road,Pudong New District,Shanghai
Yantai Derun Liquid Crystal Materials Co. Ltd.
website:http://www.ytderun.com
Contact:86-535-6300169
Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI
Doi:10.1246/cl.1982.1903
(1982)Doi:10.1016/00404-0399(50)1261-F
(1995)Doi:10.1016/j.tetlet.2018.02.082
(2018)Doi:10.1021/acs.jcim.6b00763
(2017)Doi:10.1021/ja051406k
(2005)Doi:10.1021/acs.orglett.5b02270
(2015)