A new route to aminosugars from sugar nitrones: Synthesis of 6-deoxynojirimycin

DOI: 10.1016/S0957-4166(97)00147-X

Source and publish data:

Tetrahedron Asymmetry p. 1475 - 1486 (1997)

Update date:2022-09-26

Topics:

Authors:

Dhavale, Dilip D.

Desai, Vijaya N.

Sindkhedkar, Milind D.

Mali, Raghao S.

Castellari, Carlo

Trombini, Claudio

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Article abstract of DOI:10.1016/S0957-4166(97)00147-X

The 1,3-addition of methylmagnesium chloride to dialdose derived nitrones 3 and 7 afforded N-benzylhydroxylamines 4/5 and 8/9, respectively, in high yields. The stereoselectivity of the addition was improved by the use of trimethylsilyl triflate. The N-O

Full text of DOI:10.1016/S0957-4166(97)00147-X

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