Anomalous Horner-Wadsworth-Emmons reactions on 3,4-enuloses

DOI: 10.1016/S0040-4020(97)00425-0

Source and publish data:

Tetrahedron p. 7397 - 7402 (1997)

Update date:2022-08-05

Topics:

Authors:

Moradei, Oscar M.

Du Mortier, Cecile M.

Cirelli, Alicia Fernandez

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Article abstract of DOI:10.1016/S0040-4020(97)00425-0

Pyranosic enuloses were subjected to Horner-Wadsworth-Emmons (HWE) conditions using the enolate of dimethyl(methoxycarbonyl)methyl phosphonate and its ethyl analogue. 3-O-Phosphorylation of the products as well as an unusual stereospecificity were observe

Full text of DOI:10.1016/S0040-4020(97)00425-0

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