Structural aspects of tertiary amine adducts of alane and gallane

DOI: 10.1016/s0020-1693(97)05465-0

Source and publish data:

Inorganica Chimica Acta p. 249 - 255 (1997)

Update date:2022-09-26

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Authors:

Andrews, Philip C.

Gardiner, Michael G.

Raston, Colin L.

Tolhurst, Vicki-Anne

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Article abstract of DOI:10.1016/s0020-1693(97)05465-0

Structures of N-bound alane (AlH₃) and gallane (GaH₃) are reported: the dimethylbenzylamine adduct of gallane, [(PhCH₂(Me)₂NGaH₃], which is monomeric with four-coordinate Ga, and the first chlorine containing amino complex of alane, [ClCH₂CH₂CH₂(Me)₂NAlH ₃]₂, revealing that hydride bridging is favoured over Al-Cl interaction in Al obtaining a five-coordination environment. Also presented is a reinvestigation of the previously poorly defined structural determination of the trimethylamine adduct of gallane, [Me₃NGaH₃].

Full text of DOI:10.1016/s0020-1693(97)05465-0

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