Opening of cyclopropyl ketones with SmI2 . Synthesis of spirocyclic and bicyclic ketones by intramolecular trapping of an electrophile

DOI: 10.1016/S0040-4020(97)00499-7

Source and publish data:

Tetrahedron p. 8067 - 8084 (1997)

Update date:2022-09-26

Topics:

Authors:

Molander, Gary A.

Alonso-Alija, Cristina

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(97)00499-7

A method for the opening of cyclopropyl ketones with samarium (II) iodide followed by the intramolecular trapping of an electrophile is described. This process leads to the obtainment of functionalized spirocyclic, bicyclic, and tricyclic ketones in moderate to good yields.

Full text of DOI:10.1016/S0040-4020(97)00499-7

Products guided by the article

Product name:1,3-Butanedione, 4-(2-cyclohexen-1-yl)-1-phenyl-

Cas No:193023-26-6

R&D Labs maybe for 193023-26-6

Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
Guangzhou Chemical Reagent Factory

Contact:+86-20-8435 9820 or 8435 7345

Address:Southern Guangzhou, Guangdong, China
Hubei Sky Lake Chemical Co., Ltd.

Contact:+86-27-87385545

Address:Te-2, Xijiao Chemical Park, Yuekou Town, Tianmen, Hubei, China.
Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
Xi'an Unique Electronic and Chemical Co., Ltd.

Contact:+86-029-88238008

Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA

Relevant to this article

Synthesis and solution studies of Cu(II) complexes with pyridine derivatives of iminobisphosphonic acids

Doi:10.1016/j.ica.2010.09.045
(2011)
Synthesis of amido-N-imidazolium salts and their applications as ligands in suzuki-miyaura reactions: Coupling of hetero- aromatic halides and the synthesis of milrinone and irbesartan

Doi:10.1002/adsc.201000592
(2010)
Direct synthesis of organic azides from primary amines with 2-azido-1,3-dimethylimidazolinium hexafluorophosphate

Doi:10.1002/ejoc.201001509
(2011)
PERACETYLATED CHITOBIOSE: PREPARATION BY SPECIFIC DEGRADATIONS OF CHITIN, AND CHEMICAL MANIPULATIONS

Doi:10.1016/0008-6215(89)85021-9
(1989)
Transition-Metal-Free Access to Pyridocarbazoles from 2-Alkynylindole-3-carbaldehydes via Azomethine Ylide

Doi:10.1021/acs.joc.8b00980
(2018)
A vanadium porphyrin with temperature-dependent phase transformation: Synthesis, crystal structures, supramolecular motifs and properties

Doi:10.1002/asia.201000822
(2011)

Article Doi