Chemical and Pharmaceutical Bulletin p. 1524 - 1526 (1997)
Update date:2022-09-26
Topics:
Fuji, Kaoru
Sakurai, Minoru
Kinoshita, Takayoshi
Tada, Toshiji
Kuroda, Akio
Kawabata, Takeo
A monodentate phosphine, 8-diphenylphosphino-8'-methoxy-1,1'-binaphthyl, was shown to be active as a ligand in palladium-catalyzed reactions, including the reduction of allylic carbonates with formic acid, hydrosilylation of a terminal olefin, and hydroboration of but-1-en-3-yne, even though it has a highly hindered lone pair.
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