Tetrahedron Letters p. 5297 - 5300 (1997)
Update date:2022-08-05
Topics: Characterization Protecting groups Subsequent Transformations Starting Material Selection Further Elaboration Isomer Separation
Crousse, Benoit
Alami, Mouad
Linstrumelle, Gerard
Stereoselective reduction of conjugated homopropargylic alcohols 1 followed by an elimination reaction, allows an efficient approach to stereodefined (E,E,E)-chlorotrienes. The interest of these chlorotrienes was illustrated by a stereocontrolled synthesis of navenone B and all E conjugated polyenes (trienes, tetraenes and hexaenes).
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