A short synthesis of (1S,2R)- and (1R,2R)-[1-2H]-glycerols

DOI: 10.1016/S0957-4166(97)00219-X

Source and publish data:

Tetrahedron Asymmetry p. 2325 - 2330 (1997)

Update date:2022-08-05

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Authors:

Nieschalk, Jens

O'Hagan, David

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Article abstract of DOI:10.1016/S0957-4166(97)00219-X

A straightforward three step route to (1S,2R)- and (1R,2R)-[²H]-glycerols 1a and 1b is reported. The key asymmetric step involves an AD-mix-β dihydroxylation on deuterium labelled Z- and E-allyl benzoates 4a and 4b. The route should facilitate

Full text of DOI:10.1016/S0957-4166(97)00219-X

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Product name:(3(S)-²H)-2(R),3-dihydroxypropyl benzoate

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