Tetrahedron Letters p. 5937 - 5940 (1997)
Update date:2022-08-03
Topics:
Dieter, R. Karl
Sharma, Ram R.
Allylic amines can be prepared stereospecifically via a coupling reaction of vinyl iodides and α-aminoalkylcuprates prepared from the corresponding lithium reagents and LiCl solubilized CuCN. The reaction works well for both E and Z dialkyl substituted vinyl iodides. 1-Iodoalkynes can also be coupled in modest yields to afford propargyl amines.
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(2017)
