Journal of the American Chemical Society p. 5448 - 5450 (1985)
Update date:2022-07-30
Topics:
Kazandjian, Rafi Z.
Klibanov, Alexander M.
Mushroom polyphenol oxidase can catalyze the oxidation of a number of phenols to o-quinones in chloroform.While in water the enzymatic oxidation results in negligible yields due to rapid inactivation of the enzyme and spontaneous polymerization of the quinones, in chloroform a quantitative conversion has been achieved; the quinones produced have been nonenzymatically reduced to catechols, thereby affording a net regioselective polyphenol oxidase catalyzed hydroxylation of phenols.
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