Enantiomerically pure γ-oxidofunctionalised organolithium compounds from chiral oxetanes

DOI: 10.1016/S0957-4166(97)00274-7

Source and publish data:

Tetrahedron Asymmetry p. 2633 - 2643 (1997)

Update date:2022-08-03

Topics:

Authors:

Bachki, Abderrazak

Falvello, Larry R.

Foubelo, Francisco

Yus, Miguel

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Article abstract of DOI:10.1016/S0957-4166(97)00274-7

The reductive opening of chiral oxetanes 1, ent-1, 4 and 7 with lithium powder and a catalytic amount of DTBB (5 mol%) in THF at 0°C or -20°C, followed by treatment with different electrophiles [H₂O, D₂O, Bu(t)CHO, PhCHO, Me_{2
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Full text of DOI:10.1016/S0957-4166(97)00274-7

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