Synthesis of 1-hydroxybicyclo[3.2.1]oct-3-en-2-ones by Acyloin rearrangement of 1-methoxy- or 1-tert-butyldimethylsilyloxybicyclo [2.2.2] oct-5-en-2-ones

DOI: 10.1248/cpb.45.1419

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1419 - 1427 (1997)

Update date:2022-08-05

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Authors:

Katayama, Sadamu

Hiramatsu, Hajime

Aoe, Keiichi

Yamauchi, Masashige

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Article abstract of DOI:10.1248/cpb.45.1419

1-Hydroxy-or 1,8-dihydroxy-bicyclo[3,2,1]oct-3-en-2-ones were obtained from 1-methoxy- or 1-tert-butyldimethylsilyloxy-bicyclo[2,2,2]oct-5-en-2- ones via successive processes involving demethylation or desilylation and acyloin rearrangement by reaction wi

Full text of DOI:10.1248/cpb.45.1419

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