Synthesis of 1-hydroxybicyclo[3.2.1]oct-3-en-2-ones by Acyloin rearrangement of 1-methoxy- or 1-tert-butyldimethylsilyloxybicyclo [2.2.2] oct-5-en-2-ones

DOI: 10.1248/cpb.45.1419

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1419 - 1427 (1997)

Update date:2022-08-05

Topics:

Authors:

Katayama, Sadamu

Hiramatsu, Hajime

Aoe, Keiichi

Yamauchi, Masashige

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.45.1419

1-Hydroxy-or 1,8-dihydroxy-bicyclo[3,2,1]oct-3-en-2-ones were obtained from 1-methoxy- or 1-tert-butyldimethylsilyloxy-bicyclo[2,2,2]oct-5-en-2- ones via successive processes involving demethylation or desilylation and acyloin rearrangement by reaction wi

Full text of DOI:10.1248/cpb.45.1419

NII-Electronic Library Service

Products guided by the article

Product name:2,6-Bis-(t-butyl dimethylsilyloxy) phenol

Cas No:197014-35-0

R&D Labs maybe for 197014-35-0

Shanghai Run-Biotech Co., Ltd.

website:http://www.run-biotech.com

Contact:+86-21-31576854/57171705 / 57171706

Address:second floor, building 3, No.999, jiangyue Road, minghang District, Shanghai, China
Nantong Chem-land Co., Ltd.

Contact:86 513 85512619

Address:Rm.1306, Building A, Wenfeng Mansion,168 Gongnong Road, Nantong Jiangsu China
Tangshan Moneide Trading Co., Ltd.

Contact:+86-315-8309571

Address:2-7-420 Jidong Building Materials Commercial Center, Tangshan, Hebei, 064000 China
Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
Airsea(Taizhou) Pharmaceutical Limited(expird)

Contact:+86-576-88057622

Address:Dubei, Duqiao, Linhai, Taizhou, Zhejiang, China Zip: 317016

Relevant to this article

Carbenoid reactions of trifluoromethylelement compounds. Part 4. Reactions of trifluoromethylzinc bromide with enamines and methylene bases

Doi:10.1016/0022-1139(94)03114-F
(1995)
Doi:10.1021/ja00719a026
(1970)
Reaction of [tris(trimethylsilyl)methyl]tribromogermane with magnesium: Generation of a bromogermylene

Doi:10.1021/om970371x
(1997)
Conformation, Inversion Barrier, and Solvent-Induced Conformational Shift in Exo- and Endo/Exo-Calix[4]arenes

Doi:10.1021/jo970967u
(1997)
Oxidation of Aromatic Aldehydes to Esters: A Sulfate Radical Redox System

Doi:10.1021/acs.joc.6b02775
(2017)
Synthesis and biological evaluation of novel gigantol derivatives as potential agents in prevention of diabetic cataract

Doi:10.1371/journal.pone.0141092
(2015)

Article Doi