Journal of Fluorine Chemistry p. 181 - 186 (1995)
Update date:2022-08-05
Topics:
Tyrra, Wieland
Naumann, Dieter
Pasenok, Sergej V.
Yagupolskii, Yurii L.
The reactions of ZnBr(CF3)*2CH3CN with 1-morpholinocyclo-pentene and -hexene have been investigated and found to yield mixtures of two isomers of 1-morpholino-1-cyanomethyl-2-difluoromethyl-cyclopentane and -hexane, respectively.The interaction with methylene bases of nitrogen heterocycles leads to the formation of trimethinecyanine dyes.This reaction sequence includes the formation of two carbon-carbon bonds in a one-pot operation.The mechanism of the reaction is discussed. - Keywords: Carbenoid reactions; Trifluoromethylelement compounds; Trifluoromethylzinc bromide; Enamines; Methylene bases; NMR spectroscopy; Mass spectrometry; UV-vis spectroscopy
View MoreContact:+86-21-61318535
Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
NINGBO YINZHOU PRECISE COLOR CO.,LTD.
Contact:86-574-88139809 86-574-83033159
Address:Qiming Road,Yinzhou,Ningbo,China
Mollt Biochem Co., Ltd(expird)
Contact:+86-21-38682181
Address:shanghai ,china
Sinoway International (Jiangsu) Co., Ltd.
Contact:+86-25-86630167
Address:17 Beijing Road (West), Nanjing, China
Contact:0550-7041128 0550-7090578
Address:Wangdian Street,Xinjie Town
Doi:10.1021/ja972340z
(1997)Doi:10.1016/j.bmcl.2013.08.021
(2013)Doi:10.1021/ja961329g
(1996)Doi:10.1021/om970581+
(1997)Doi:10.1016/S0957-4166(97)00323-6
(1997)Doi:10.1039/P19720002079
(1972)
