Tetrahedron Letters p. 6533 - 6536 (1997)
Update date:2022-08-02
Topics: Stereocontrolled Experimental method Regiocontrolled
Hay, Lynne A.
Mitchell, David
Palladium-catalyzed hydroarylation of acetylenes provides regio- and stereodefined olefins. This methodology has been extended to arylpropiolamides where 3,3-diarylacrylamides are prepared stereospecifically. In an independent fashion, both the E- and Z-isomers were prepared by judicious choice of arylpropiolamide preparation and the palladium catalyzed hydroarylation reaction.
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