Tetrahedron Letters p. 6493 - 6496 (1997)
Update date:2022-08-03
Topics:
Bryan, Vernal J.
Chan, Tak-Hang
Indium mediated coupling of allylic bromide with acyloyl-imidazoles or pyrazoles in aqueous media gives the corresponding tertiary alcohols or ketones in good yield. The reaction provides a facile regioselective synthesis of P,β,γ-unsaturated ketones and its usefulness is demonstrated by the synthesis of the monoterpene artemesia ketone.
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