Unimolecular Chain Transfer (UMCT) Reactions of Silicon Hydrides: Controlling Relative Configuration in Hydrogen Transfer Reactions of Cyclic Radicals

DOI: 10.1055/s-1997-1546

Source and publish data:

Synlett p. 1102 - 1104 (1997)

Update date:2022-08-04

Topics:

Authors:

Curran, Dennis P.

Xu, Jinyou

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1997-1546

UMCT-controlled sequences of radical cyclization followed by 1,5-hydrogen transfer from diphenylsilanes or bis(trimethylsilyl)-silanes are introduced. The later silanes have improved reactivity.

Full text of DOI:10.1055/s-1997-1546

Products guided by the article

Product name:Acetic acid 5-(tert-butyl-dimethyl-silanyloxy)-1-cyclohex-1-enyl-pentyl ester

Cas No:197721-51-0

R&D Labs maybe for 197721-51-0

Guarson Chemical Co., Ltd.

website:http://www.guarson.com

Contact:+86-523-88059600,+86-13805268803

Address:Room B1006,Yafang Building,Jiangyan Avenue,Jiangyan District, Taizhou City,Jiangsu,China
Pengchen New Material Technology Co., Ltd.

Contact:+86-512-63680537

Address:99.6 km of national road 318, Meiyan Community,Pingwang Town, Wujiang District, Suzhou 215225
YanCheng LongShen Chemical Co.,Ltd.

Contact:+86-515-86668866

Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
Reliable Pharma Technology (Shanghai) Co., Ltd.

Contact:0086-21-67676847-8008

Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.

Relevant to this article

Combining Orthogonal Chain-End Deprotections and Thiol–Maleimide Michael Coupling: Engineering Discrete Oligomers by an Iterative Growth Strategy

Doi:10.1002/anie.201706522
(2017)
Formation of smectic and columnar liquid crystalline phases by cyclotriveratrylene (CTV) and cyclotetraveratrylene (CTTV) derivatives incorporating calamitic structural units

Doi:10.1039/a702034a
(1997)
Doi:10.1246/bcsj.41.1638
(1968)
Multisubstrate analogue based on 5,8,10-trideazafolate

Doi:10.1016/S0968-0896(97)00124-7
(1997)
Reactions of Carbonyl Compounds in Basic Solutions. Part 30.¹ the Effect of 2-Formyl, 2,6-Diformyl and 2-Trifluoroacetyl Substituents on the Alkaline and Neutral Hydrolysis of Methyl Benzoate and Phenyl Acetate

Doi:10.1039/a703218h
(1997)
Binding and redox properties of iron(II) bonded to an oxo surface modeled by calix[4]arene

Doi:10.1021/ic991467h
(2000)

Article Doi