Unimolecular Chain Transfer (UMCT) Reactions of Silicon Hydrides: Controlling Relative Configuration in Hydrogen Transfer Reactions of Cyclic Radicals

DOI: 10.1055/s-1997-1546

Source and publish data:

Synlett p. 1102 - 1104 (1997)

Update date:2022-08-04

Topics:

Authors:

Curran, Dennis P.

Xu, Jinyou

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Article abstract of DOI:10.1055/s-1997-1546

UMCT-controlled sequences of radical cyclization followed by 1,5-hydrogen transfer from diphenylsilanes or bis(trimethylsilyl)-silanes are introduced. The later silanes have improved reactivity.

Full text of DOI:10.1055/s-1997-1546

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