Benzylfluorocarbene: Reactions and kinetics

DOI: 10.1016/S0040-4039(97)01709-7

Source and publish data:

Tetrahedron Letters p. 7049 - 7052 (1997)

Update date:2022-09-26

Topics:

Authors:

Moss, Robert A.

Maksimovic, Ljiljana

Merrer, Dina C.

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Article abstract of DOI:10.1016/S0040-4039(97)01709-7

Benzylfluorocarbene, generated from the corresponding diazirine, is accompanied by considerable azine formation. Its rearrangement to β-fluorostyrene isomers in tetrachloroethane is characterized by E(a) = 3.2 kcal/mol and log A = 9.5 s^-1.

Full text of DOI:10.1016/S0040-4039(97)01709-7

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Product name:3H-Diazirine,3-fluoro-3-(phenylmethyl)-(9CI)

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