Benzylfluorocarbene: Reactions and kinetics

DOI: 10.1016/S0040-4039(97)01709-7

Source and publish data:

Tetrahedron Letters p. 7049 - 7052 (1997)

Update date:2022-09-26

Topics:

Authors:

Moss, Robert A.

Maksimovic, Ljiljana

Merrer, Dina C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)01709-7

Benzylfluorocarbene, generated from the corresponding diazirine, is accompanied by considerable azine formation. Its rearrangement to β-fluorostyrene isomers in tetrachloroethane is characterized by E(a) = 3.2 kcal/mol and log A = 9.5 s^-1.

Full text of DOI:10.1016/S0040-4039(97)01709-7

Products guided by the article

Product name:3H-Diazirine,3-fluoro-3-(phenylmethyl)-(9CI)

Cas No:198020-05-2

R&D Labs maybe for 198020-05-2

Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
Xiamen Kaijia Imp & Exp Co., Ltd.

Contact:86-592-5101177

Address:Room406 Luhui Building No. 65 Haitian Road Huli Xiamen,China.
Shanghai Apeptide Co., Ltd.

website:http://www.apeptides.com/en/

Contact:+86-21-60871011

Address:No. 80 Chuanshan Shuyuan Steet,Pudong,Shanghai
Shanghai Hope Chem Co., Ltd

website:http://www.hope-chem.com

Contact:86-21-58090396-805

Address:Floor 4, Building 5, No.588 Tianxiong Road, Zhoupu International Medical Zone, ShangHai, China
Liaoning Yufeng Chemical Co.,Ltd.

Contact:86-0419-3418888

Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China

Relevant to this article

Titanium-catalyzed Reformatsky-type reaction

Doi:10.1016/j.jorganchem.2007.02.037
(2007)
3,4-dihydro-1-isoquinolinamines: A novel class of nitric oxide synthase inhibitors with a range of isoform selectivity and potency

Doi:10.1016/S0960-894X(01)00119-6
(2001)
Doi:10.1139/v68-500
(1968)
Synthese von [cis-(bipy)Pt(C<*>CPh)2]AgFBF3 und dessen Reaktionsverhalten gegenueber Lewis-Basen; die Festkoerperstruktur von cis-(bipy)Pt(C<*>CPh)2 und [(bipy)Pt(C<*>CPh)(PPh3)]BF4

Doi:10.1016/S0022-328X(03)00777-0
(2003)
Syntheses of 2,6-anhydro-3-deoxy-5-O-phosphono-3-tetradecanamido-4-O- [(R)-3-(tetradecanoyloxy)tetradecanoyl]-D-glycero-D-ido-heptonic acid, its dimeric analogue, and related compounds

Doi:10.1016/S0040-4020(97)10063-1
(1997)
New neutral and anionic alkynylgold(I) complexes via new synthetic methods. Crystal and molecular structures of [Au(C≡CSiMe₃)(CN^tBu)], and [Au(C≡CR)PR′₃] (R′ = cyclohexyl, R = CH₂Cl, CH₂Br; R′ = Ph, R = SiMe₃, ^tBu)

Doi:10.1021/om970725k
(1997)

Article Doi