Benzylfluorocarbene: Reactions and kinetics

DOI: 10.1016/S0040-4039(97)01709-7

Source and publish data:

Tetrahedron Letters p. 7049 - 7052 (1997)

Update date:2022-09-26

Topics:

Authors:

Moss, Robert A.

Maksimovic, Ljiljana

Merrer, Dina C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)01709-7

Benzylfluorocarbene, generated from the corresponding diazirine, is accompanied by considerable azine formation. Its rearrangement to β-fluorostyrene isomers in tetrachloroethane is characterized by E(a) = 3.2 kcal/mol and log A = 9.5 s^-1.

Full text of DOI:10.1016/S0040-4039(97)01709-7

Products guided by the article

Product name:3H-Diazirine,3-fluoro-3-(phenylmethyl)-(9CI)

Cas No:198020-05-2

R&D Labs maybe for 198020-05-2

JIAXING SUNS INTERNATIONAL TRADE CO LTD

Contact:18367306858

Address:No.123,Huixin Avenue,Huimin Dist
Shanghai Intime pharm Co.,Ltd

Contact:86-21-58226973

Address:No 351,Guoshoujing Road, Zhangjiang Hi-tech Park, Pudong, Shanghai, China
Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road
Suzhou Sibian Chemical Technology Co., Ltd

website:http://www.sibianpharm.com

Contact:+8618169181984,+8618013186906

Address:Room1404,BuildingA,Jiabao Square No.323 Baodai East Road,Wuzhong District,Suzhou Jiangsu China (215128)
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China

Relevant to this article

Titanium-catalyzed Reformatsky-type reaction

Doi:10.1016/j.jorganchem.2007.02.037
(2007)
3,4-dihydro-1-isoquinolinamines: A novel class of nitric oxide synthase inhibitors with a range of isoform selectivity and potency

Doi:10.1016/S0960-894X(01)00119-6
(2001)
Doi:10.1139/v68-500
(1968)
Synthese von [cis-(bipy)Pt(C<*>CPh)2]AgFBF3 und dessen Reaktionsverhalten gegenueber Lewis-Basen; die Festkoerperstruktur von cis-(bipy)Pt(C<*>CPh)2 und [(bipy)Pt(C<*>CPh)(PPh3)]BF4

Doi:10.1016/S0022-328X(03)00777-0
(2003)
Syntheses of 2,6-anhydro-3-deoxy-5-O-phosphono-3-tetradecanamido-4-O- [(R)-3-(tetradecanoyloxy)tetradecanoyl]-D-glycero-D-ido-heptonic acid, its dimeric analogue, and related compounds

Doi:10.1016/S0040-4020(97)10063-1
(1997)
New neutral and anionic alkynylgold(I) complexes via new synthetic methods. Crystal and molecular structures of [Au(C≡CSiMe₃)(CN^tBu)], and [Au(C≡CR)PR′₃] (R′ = cyclohexyl, R = CH₂Cl, CH₂Br; R′ = Ph, R = SiMe₃, ^tBu)

Doi:10.1021/om970725k
(1997)

Article Doi