Intramolecular electron transfer in mixed-valence biferrocenium salts containing heteroatoms: Preparation, structure, and 57Fe m?ssbauer characteristics

DOI: 10.1021/om970746e

Source and publish data:

Organometallics p. 5816 - 5825 (1997)

Update date:2022-08-03

Topics:

Authors:

Dong, Teng-Yuan

Chang, Chung-Kay

Lee, Shu-Hwei

Lai, Long-Li

Chiang, Michael Yen-Nan

Lin, Kuan-Jiuh

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Article abstract of DOI:10.1021/om970746e

A convenient new method is developed for the preparation of 1′,1?-disubstituted biferrocenes which can be oxidized with iodine to a new series of mixed-valence compounds. The X-ray structures of 1′,1?-dimethoxymethyl, 1′,1?-diethoxyl, 1′,1?-dimethyl, 1′,1?-dihydroxymethyl, 1′,1?-dibenzoyloxymethyl, 1′,1?-dimethylthio, and 1′,1?-diethylthio neutral biferrocenes and the mixed-valence 1′,1?-diethoxyl, 1′,1?-dimethyl, 1′,1?-dibenzoyloxymethyl, and 1′,1?-diphenylthio biferrocenium triiodide salts have been determined at 298 K. The rates of intramolecular electron transfer in these mixed-valence cations were estimated by variable-temperature ⁵⁷Fe M?ssbauer experiment.

Full text of DOI:10.1021/om970746e

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