Chemistry Letters p. 1151 - 1152 (1997)
Update date:2022-07-30
Topics:
Matsumoto, Kazutsugu
Shimojo, Megumi
Hatanaka, Minoru
PPL catalyzes the hydrolysis of racemic five-membered cyclic carbonates bearing a long chain with high enantioselectivity. Optically pure (S)-(+)-8-hydroxyhexadecanoic acid is effectively synthesized starting from (R)-4-(7-benzyloxy)heptyl-1,3-dioxolan-2-one and (S)-9-benzyloxynonane-1,2-diol, which are prepared via an enzymatic reaction.
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