Polyfluoroalkoxylation and methoxylation of polychloropyridines

DOI: 10.1016/S0022-1139(97)00094-8

Source and publish data:

Journal of Fluorine Chemistry p. 9 - 13 (1998)

Update date:2022-08-02

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Authors:

Xu, Xiaoyong

Qian, Xuhong

Li, Zhong

Song, Gonghua

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Article abstract of DOI:10.1016/S0022-1139(97)00094-8

With sodium 2,2,2-trifluoroethoxide, sodium 1,1,1,3,3,3-hexafluoro-2-propoxide and sodium methoxide used as nucleophilic reagents, the alcoholysis reactions of 2,3,4,5,6-pentachloropyridine and 2,3,5,6-tetrachloropyridine were studied. Some new polyfluoroalkoxypyridines have been synthesized. The activities, pathways, mechanism of the alcoholysis reactions are discussed.

Full text of DOI:10.1016/S0022-1139(97)00094-8

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