Russian Chemical Bulletin p. 1458 - 1464 (1997)
Update date:2022-07-29
Topics:
Kreindlin
Rybinskaya
Petrovskii
The [(Me2CC5H4)2M]2+ and [(Me(H)CC5H4)2M]2+ dications (M = Ru, Os) were generated and their precursors, dicarbinols, were synthesized. 1H NMR spectral analysis showed that the former dications have a dicarbocation structure. For the [(Me(H)CC5H4)2M]2+ dications, the energies of both the onium and dicarbocation structures are close, and compounds of both types can be simultaneously observed in solution.
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Doi:10.1002/jccs.201700054
(2017)Doi:10.1016/S0040-4039(97)10499-3
(1997)Doi:10.1021/jo900361c
(2009)Doi:10.1021/om970713z
(1998)Doi:10.1016/0022-1902(81)80164-9
(1981)Doi:10.1007/BF02256759
(1997)
