Tetrahedron Letters p. 8977 - 8980 (1997)
Update date:2022-07-29
Topics:
Teng, Xin
Kasatkin, Aleksandr
Kawanaka, Yasufumi
Okamoto, Sentaro
Sato, Fumie
Chiral allyltitaniums having an amino substituent at the C-4 position are prepared from optically active allylic alcohol derivatives 1 and Ti(O-i-Pr)4/2i-PrMgCl reagent, which, in turn, react with aldehydes regio- and stereoselectively to afford 3-amino-2-vinylalkanols in excellent yields.
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(1997)
