Tetrahedron Letters p. 8659 - 8662 (1997)
Update date:2022-08-02
Topics:
Romero, Donna L.
Fritzen, Edward L.
Palladium catalyzed asymmetric allylic alkylations of a bis(trimethylsilyl) substituted propenyl acetate and carbonate were investigated using various chiral ligands and reaction conditions. The best enantioselectivity (86% e.e.) was obtained with the substrate 1-phenyl-3,3-bis(trimethylsilyl)propenyl carbonate 13 and the chiral oxazoline ligand 4c.
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