Metal-Catalyzed Organic Photoreactions. The Photooxidation of Vinylsilanes and Vinyl Sulfides in the Presence of Iron(III) Chloride, and the Regioselective Synthesis of α-Chloro Ketones

DOI: 10.1246/bcsj.56.285

Source and publish data:

Bulletin of the Chemical Society of Japan p. 285 - 286 (1983)

Update date:2022-08-05

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Authors:

Sato, Tadashi

Tonegawa, Tamotsu

Naoi, Kunio

Murayama, Eigoro

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Article abstract of DOI:10.1246/bcsj.56.285

The irradiation of a pyridine solution of vinylsilanes or vinyl sulfides in the presence of iron(III) chloride under oxygen produced α-chloro ketones, with a carbonyl group at the olefinic carbon originally bearing a silicon or sulfur atom.

Full text of DOI:10.1246/bcsj.56.285

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