Metal-Catalyzed Organic Photoreactions. The Photooxidation of Vinylsilanes and Vinyl Sulfides in the Presence of Iron(III) Chloride, and the Regioselective Synthesis of α-Chloro Ketones

DOI: 10.1246/bcsj.56.285

Source and publish data:

Bulletin of the Chemical Society of Japan p. 285 - 286 (1983)

Update date:2022-08-05

Topics:

Authors:

Sato, Tadashi

Tonegawa, Tamotsu

Naoi, Kunio

Murayama, Eigoro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.56.285

The irradiation of a pyridine solution of vinylsilanes or vinyl sulfides in the presence of iron(III) chloride under oxygen produced α-chloro ketones, with a carbonyl group at the olefinic carbon originally bearing a silicon or sulfur atom.

Full text of DOI:10.1246/bcsj.56.285

Products guided by the article

Product name:Octanal, 2-chloro-

Cas No:20334-54-7

R&D Labs maybe for 20334-54-7

Sichuan Mianzhu Ronghong Chemical Co.,LTd

Contact:8613981840544

Address:XINSHI INDUSTRY PARK,MIANZHU,SICHUAN,CHINA
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun
Zhenjiang Huayu I/E Co.,LTD

Contact:86-511-85210668 0511-85210668, 85210818, 85210898

Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Shanghai Yingrui Biopharma Co., Ltd

Contact:021-3358 8661*8003

Address:shanghai
Brichem ( Haikou ) Co. Ltd.

Contact:86-898-65311214

Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China

Relevant to this article

Microwave-assisted cyclocondensation of hydrazine derivatives with alkyl dihalides or ditosylates in aqueous media: Syntheses of pyrazole, pyrazolidine and phthalazine derivatives

Doi:10.1016/j.tetlet.2005.07.018
(2005)
Discovery of novel pyridinopolyamines with potent antimicrobial activity: Deconvolution of mixtures synthesized by solution-phase combinatorial chemistry

Doi:10.1021/jm970598u
(1998)
Cascade radical processes leading to polycycle constructions. The total synthesis of spongian-16-one

Doi:10.1016/0040-4039(96)00740-X
(1996)
The use of a planar chiral ligand to effect C-H activation with asymmetric induction at an iridium center. dramatically different C-H activation stereoselectivities for benzene and cyclohexane

Doi:10.1021/ja974323f
(1998)
2',5'-Dihydroxychalcone as a potent chemical mediator and cyclooxygenase inhibitor

Doi:10.1111/j.2042-7158.1997.tb06837.x
(1997)
Chemoselectivity in the rhodium-catalyzed hydroformylation of 4-vinylpyridine: Crucial role of phosphine ligand in promoting carbonylation instead of hydrogenation

Doi:10.1016/S0022-328X(00)00011-5
(2000)

Article Doi