Cascade radical processes leading to polycycle constructions. The total synthesis of spongian-16-one

DOI: 10.1016/0040-4039(96)00740-X

Source and publish data:

Tetrahedron Letters p. 4191 - 4194 (1996)

Update date:2022-08-05

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Authors:

Pattenden, Gerald

Roberts, Lee

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Article abstract of DOI:10.1016/0040-4039(96)00740-X

A concise total synthesis of the marine sponge metabolite spongian-16-one 1, which features a novel cascade of three consecutive 6-endo-trig radical cyclisations from a polyene acyl radical intermediate as a key step, viz 9 → 10, is described.

Full text of DOI:10.1016/0040-4039(96)00740-X

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