Tetrahedron Letters p. 4191 - 4194 (1996)
Update date:2022-08-05
Topics:
Pattenden, Gerald
Roberts, Lee
A concise total synthesis of the marine sponge metabolite spongian-16-one 1, which features a novel cascade of three consecutive 6-endo-trig radical cyclisations from a polyene acyl radical intermediate as a key step, viz 9 → 10, is described.
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