RSC Advances p. 28997 - 29007 (2018)
Update date:2022-08-04
Topics: Total synthesis Cu-catalyzed
Zheng, Bo
Qu, Hui-Ya
Meng, Tian-Zhuo
Lu, Xia
Zheng, Jie
He, Yun-Gang
Fan, Qi-Qi
Shi, Xiao-Xin
Novel total syntheses of oxoaporphine alkaloids such as liriodenine, dicentrinone, cassameridine, lysicamine, oxoglaucine and O-methylmoschatoline were developed. The key step of these total syntheses is Cu-catalyzed conversion of 1-benzyl-3,4-dihydro-isoquinolines (1-Bn-DHIQs) to 1-benzoyl-isoquinolines (1-Bz-IQs) via tandem oxidation/aromatization. This novel Cu-catalyzed conversion has been studied in detail, and was successfully used for constructing the 1-Bz-IQ core.
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