Tetrahedron Letters p. 1335 - 1338 (1998)
Update date:2022-08-03
Topics:
Myers, Andrew G.
McKinstry, Lydia
Barbay, Joseph K.
Gleason, James L.
Pseudoephedrine α-fluoroacetamide (1), a nonvolatile, crystalline solid, is alkylated efficiently and with high diastereoselectivity with reactive alkyl halides. The alkylation products can be hydrolyzed under mild basic conditions to form α-fluoro carboxylates with high enantiomeric enrichment.
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