
Tetrahedron p. 2819 - 2826 (1998)
Update date:2022-08-05
Topics:
Tyvorskii, Vladimir I.
Bobrov, Denis N.
Kulinkovich, Oleg G.
De Kimpe, Norbert
Tehrani, Kourosch Abbaspour
A convenient synthesis of 5-substituted 2-perfluoroalkyl-4H-pyran-4-ones by dehydration of 2,3-dihydro-3-hydroxy-6-perfluoroalkyl-4H-pyran-4-ones is described. The 6-substituted and parent 2-perfluoroalkyl-4H-pyran-4-ones have been more successfully prepared using the condensation of alkyl enol ethers, derived from β-dicarbonyl compounds, with ethyl perfluoroalkanoates.
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Doi:10.1021/jo9720795
(1998)Doi:10.7164/antibiotics.51.378
(1998)Doi:10.1039/C19680000976
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(1998)