Asymmetric Electrophilic α-Amidoalkylation - 10: A new Camphorimide Derived Chiral Auxiliary for the Asymmetric Synthesis with N-Acyliminium Ions - Preparation of Aracemic 2-Substituted Piperidines

DOI: 10.1016/S0040-4020(01)81110-8

Source and publish data:

Tetrahedron p. 3113 - 3122 (1994)

Update date:2022-07-29

Topics:

Authors:

Wanner, Klaus Th.

Paintner, Franz F.

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Article abstract of DOI:10.1016/S0040-4020(01)81110-8

Compound 5 is a new α-amidoalkylation reagent for the asymmetric synthesis of 2-substituted piperidines.Its chiral auxiliary 3 is derived from camphoric acid and designed for an asymmetric induction mechanism featuring precomplexation as the decisive step

Full text of DOI:10.1016/S0040-4020(01)81110-8

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