Low-valent titanium mediated reductive deoxygenation of carbonyls to methylenes via carbon-nitrogen bond cleavage in N-(arylmethyl) anilines

Article abstract of DOI:10.1080/00397919608003711

The reduction of aryl aldehydes and ketones in neutral medium, to the corresponding hydrocarbons via carbon-nitrogen bond cleavage of the intermediate N-(arylmethyl) anilines with low-valent titanium reagents is described. It provides a mild, convenient and selective pathway for deoxygenation of carbonyls without the production of any side product.

Full text of DOI:10.1080/00397919608003711

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Low-Valent Titanium
Mediated Reductive
Deoxygenation of Carbonyls
to Methylenes Via Carbon-
Nitrogen Bond Cleavage in N-
(Arylmethyl) Anilines
Sanjay Talukdar a & Asoke Banerji a
a Bio-Organic Division, Bhabha Atomic Research
Centre, Bombay, 400 085, India
Published online: 21 Aug 2006.
To cite this article: Sanjay Talukdar & Asoke Banerji (1996) Low-Valent Titanium
Mediated Reductive Deoxygenation of Carbonyls to Methylenes Via Carbon-
Nitrogen Bond Cleavage in N-(Arylmethyl) Anilines, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry,
26:6, 1051-1056, DOI: 10.1080/00397919608003711
To link to this article: http://dx.doi.org/10.1080/00397919608003711
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